Ligand Field Activation Energy for Ligand Substitution in Octahedral Complexes
نویسندگان
چکیده
منابع مشابه
Universal spectrochemical series of six-coordinate octahedral metal complexes for modifying the ligand field splitting.
We studied a novel universal spectrochemical series of six-coordinated octahedral 3d transition metal complexes, which can be used for any combination of central metal atom and ligand molecules. A two dimensional spectrochemical series could be used to estimate the ligand field splitting energy of not only known compounds but also the unknown compounds. Therefore, it should be possible to contr...
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Institute of Physical Chemistry II, University of Erlangen-Nürnberg, D-8520 Erlangen, Germany (Z. Naturforsch. 29 a, 4'19—428 [1974] ; received 16 November 1973) The complete ligand-field, Coulomb interelectronic repulsion, and spin-orbit interaction matrices have been derived for the d5 electron configuration within octahedral (Oh) and tetrahedral (Td) symmetry. The calculations were performed...
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Urea Functionalized Ligand Complexes in Allylic Substitution Reactions
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1968
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.41.2817